| Addition Polymerization |
Condensation Polymerization |
| Monomer units contain double or triple bond (reactive site) which combine in succession to give a polymer. |
Monomer units contain two or more functional groups which react with each other to undergo condensation. |
| Monomers add on to yield a polymer without elimination of any by product. |
Monomers combine to form a polymer with elimination of small molecules like H2O, HCl, NH3, CH3OH. |
| It is a chain reaction. |
It is an intermolecular reaction. |
| It involves free radical or ionic mechanism. |
It follows the mechanism of condensation or esterification. |
| It leads to formation of homochain polymers. |
It leads to formation of heterochain polymers. |
| Molecular weight of polymer is an exact multiple of monomeric units. |
Molecular weight of polymer is not an exact multiple of monomeric units. |
| Generally, thermoplastics are obtained. |
Both thermoplastics and thermosets are obtained. |
| High molecular mass polymer is obtained immediately. |
Molecular mass of polymer increases steadily through the reaction. |
| Radical initiator, Lewis acid or base is required. |
Mineral acids and bases are used as catalyst. |
| Addition polymers are formed quickly. |
Reaction is completed in different independent steps taking a definite period of time. |
| Common examples are polythene, polypropylene, PVC etc. |
Common examples are terylene, bakelite etc. |