Crystalline Solids | Amorphous Solids |
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The crystalline solids have definite characteristic shape. | The amorphous solids have irregular shape. |
They have regular arrangement of the constituent particles. They are said to exhibit long range order. | They do not have any regular arrangement of the constituent particles. They may have short range order. |
They have sharp and characteristic melting point. | They do not have sharp melting point. They gradually soften over a range of temperature. |
When cut with a sharp edged tool, they split into two pieces and the newly generated surfaces are plain and smooth. | When cut with a sharp edged tool they cut into two pieces with irregular surfaces. |
They have a definite and characteristic enthalpy of fusion. | They do not have definite enthalpy of fusion. |
They are anisotropic i.e. their physical properties like mechanical strength, refractive index, electrical and thermal conductivity are different in different directions. | They are isotropic i.e. their physical properties are same in all directions. |
They are true solids. | They are pseudo solids and super cooled liquids. |
Examples – iron, silver, common salt, potassium nitrate etc. | Example – glass, rubber, plastics etc. |
Sunday, 7 May 2017
Friday, 5 May 2017
Addition Polymerization Vs Condensation Polymerization
Addition Polymerization | Condensation Polymerization |
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Monomer units contain double or triple bond (reactive site) which combine in succession to give a polymer. | Monomer units contain two or more functional groups which react with each other to undergo condensation. |
Monomers add on to yield a polymer without elimination of any by product. | Monomers combine to form a polymer with elimination of small molecules like H2O, HCl, NH3, CH3OH. |
It is a chain reaction. | It is an intermolecular reaction. |
It involves free radical or ionic mechanism. | It follows the mechanism of condensation or esterification. |
It leads to formation of homochain polymers. | It leads to formation of heterochain polymers. |
Molecular weight of polymer is an exact multiple of monomeric units. | Molecular weight of polymer is not an exact multiple of monomeric units. |
Generally, thermoplastics are obtained. | Both thermoplastics and thermosets are obtained. |
High molecular mass polymer is obtained immediately. | Molecular mass of polymer increases steadily through the reaction. |
Radical initiator, Lewis acid or base is required. | Mineral acids and bases are used as catalyst. |
Addition polymers are formed quickly. | Reaction is completed in different independent steps taking a definite period of time. |
Common examples are polythene, polypropylene, PVC etc. | Common examples are terylene, bakelite etc. |
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