| Sigma (σ) Bond | Pi (π) Bond |
|---|---|
| A sigma bond is formed by the end to end filled atomic orbitals along the internuclear axis. The overlapping involves two s-orbitals, one s and p-orbital or two p-orbitals. | A pi-bond is formed by the sidewise overlap of two half-filled p-orbitals. |
| In this case, the overlapping can take place to a larger extent and therefore, the bond formed is a strong bond. | In the formation of π-bond the overlapping occurs to a lesser extent and therefore, the bond is weak. |
| The molecular orbital is symmetrical about the internuclear axis. | The molecular orbital is discontinuous and consists of two charged clouds above and below the plane of atoms. |
| There can be free rotation of atoms around the σ-bond. | Because of overlapping of the electron clouds above and below the plane of the atoms, free rotation of atoms around π-bond is not possible. |
| The bond may be present between two atoms either alone or along with π-bond. | The bond is always present between two atoms in addition to sigma bond. |
| In the formation of sigma bond, s-orbitals can participate. | s-orbitals cannot participate in the formation of pi-bond. |
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