Ideal Solution | Non-Ideal Solution |
---|---|
The interactions between the components are similar to those in the pure components. | The interaction between the components are different from those of the pure components. |
There is no enthalpy change on mixing (ΔmixingH = 0). | There is enthalpy change on mixing (ΔmixingH ≠ 0). |
There is no volume change on mixing (ΔmixingV = 0). | There is volume change on mixing (ΔmixingV ≠ 0). |
Each component obeys Raoult’s law at all temperatures and concentrations, i.e. pA = pA° × xA and pB = pB° × xB where pA and pB are the vapour pressures of the components in the solution. |
Their components do not obey Raoult’s law. They show positive and negative deviations from Raoult’s law, i.e. pA ≠ pA° × xA and pB ≠ pB° × xB where pA° is the vapour pressure of the pure component A and pB° is the vapour pressure of pure component B at the same temperature. |
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